I dump used ATF into the holes covered by the rubber plugs in the B and C pillars. I believe it goes down, sits on top of the foam in the pillars/dogleg area, seeps down between the foam and sheet metal. Also, remove rear speakers and you have access to the wheelhouse, dogleg and rear quarter panel areas. You can also dump ATF or similar into the sliding door tracks, place you van in a nose high orientation (on a hill) and watch the product drip out the pinch weld all along the rocker. Turn the van around on the hill and it drips out of the other section of rocker pinch weld. Buckets or eavestrough (Jeepman's idea) are good to catch what's dripping out. IMO, rust happens where water pools. Thin ATF of other rustproofing pools in the same places that water does and rust occurs, plus displaces water from folded seams and wicks upwards, protecting metal.
I had a 2006 DGC, live 60 feet from the ocean in Atlantic Canada and had no rust on my van, while all others around here were rotted out in the rear rocker and dogleg areas. Salt spray on our roads and highways - thrown up by other vehicles - soaks our vehicles and it seeps down past rubber window seals etc. Heat and cold cycles - IMO - cause inner panel condensation. Although it doesn't seem to be the case here, a lot of people just spray undercoating on the exterior of the chassis and don't know to spray it in interior panels where it really works. I do undercoat the chassis too with a thicker product.
I am going to experiment with biodegradable rustproofing. I picked up a jug of Canola oil and a liter of acetone. The ratio is 10:1 (oil to acetone). I'm doing this, not because I am an environmentalist, but because it's cheap and reportedly very effective. Of course, I'd rather have veggie oil on my driveway than petroleum-based stuff. I am also picking up some wax toilet rings and mineral spirits and will make my own wax/oil-based solution. I believe that a wax-based product is the only thing that stands a chance of not getting washed away in such areas as wheel wells, suspension components, exposed chassis areas etc.