I'm glad at least one of them works now! That's definitely weird for "new" Fobiks for sure, they're probably rebuilt or cheaper aftermarket Fobiks.
Curiously, the second key only starts the vehicle - none of the other key functions work.
That's definitely weird, does it make a clicking sound when you press down on the buttons?
There are a few possibilities for this, from most likely to least likely.
1. Is the van giving a battery low message on the EVIC? The battery in the Fobik could be worn down enough to not allow it to communicate with the van from a distance, but still start it.
2. The Fobik was improperly programmed, only allowing it to start the van and nothing else.
3. Somehow all of the contacts on the circuit board could be dirty, that could've definitely happened if these Fobiks were rebuilt with new shells/buttons, usually just wiping them with a dry cloth, alcohol, or contact/electronic cleaner (in severe cases) can get any stubborn dirt off.
4. The circuit board in the Fobik itself could be damaged/defective.
If these were truly new (OEM or Aftermarket) Fobiks, I'm going to guess that one of them could've been improperly programmed? If this is the case, you could spend money on AlfaOBD or AppCar-DiagFCA and a compatible OBD-II Scanner (Like Veepeak), or you can have a locksmith and/or dealer reprogram it for you. If you would happen to do that yourself, I can give more information on that later.
If these are rebuilt Fobiks, with new shells and rubber buttons, I'd guess that they either missed out on replacing the battery, they could've improperly seated the rubber buttons (you might notice this if the buttons are hard to press/don't make a noise), or the contacts could be dirty. I'd probably recommend taking apart the non-working key fob and inspect the internals for anything out of the ordinary.